1. Definition
Let X_1, X_2, \cdots be a Markov chain with transition probabilities P_{ij}.P_{ij} = Pr\{X_{n+1} = j| X_n = i\}
E.g. A sample realization is 1, 2, 3, 4, 5
Let X_n, x_{n-1}, \cdots be the same sequence in reverse, i.e. \cdots, 5, 4, 3, 2, 1, \cdots
Let Q_{ij} be the transition probabilities of the reversed process. That is
Q_{ij} = Pr\{X_{n-1} = j |X_n = i\}
= \frac{Pr\{X_{n-1} =j, X_n = i\}}{Pr\{X_n = i\}}
= \frac{Pr\{X_{n-1} = j\} Pr\{X_n =i | X_{n-1} = j\}}{Pr\{X_n = i\}}
= \frac{Pr\{X_{n-1} = j\} P_{ji}}{Pr\{X_n = i\}}
2. Conclusion
In the steady state, assuming the limiting probabilities exist, we haveQ_{ij} = \frac{\pi_j P_{ji}}{\pi_i} or \pi_i Q_{ij} = \pi_j Q_{ji}
The above equation is saying that the rate of transmissions from i to j in the reversed chain is equal to the rate of transitions from j to i in the forward chain.
A DTMC is time reversible if Q_{ij} = P_{ij}
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